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PSV v Napoli : Champions League match betting preview, prediction and odds

Tue 21st Oct, 20:00 BST, Philips Stadion, Eindhoven

the Philips Stadion is the setting on Tuesday night, as Peter Bosz's PSV welcome Antonio Conte's Napoli in the Champions League. We want to see our users winning on this match, so every statistics you could ever need to make a smart selection is published below. Go between 17 markets or take our top tip. We have predictions, head to head (H2H) analysis and odds from leading bookmakers for every one.

Want to know who’s consistently beating the odds? Check out the Top Champions League Tipsters and see the most profitable experts for this season!

If you’re keen on betting across various leagues and markets, our Live Bets page showcases active accumulator bets and real-time tips.

Best Tip: Both teams to score

Studying the KickOff match predictions, bookmakers' odds and relevant statistics, there's one market that seems hard to ignore for this tie: both teams to score. In PSV and Napoli we have two sides going head-to-head that regularly score, but equally have trouble shutting the opposition out, and we expect them to show themselves again on Tuesday night. BTTS – yes best odds: 1.55.

An away win looks like the most likely outcome in the win/draw/win market, with our predictive algorithm suggesting there’s a 46% chance of Napoli coming away with a win.

Checkout the hundreds of tips picked but our top win/draw/win tipsters

Predictions	Bet365	Coral
PSV 31%	9/4 2%	2/1 3%
Draw 24%	23/10	27/10 3%
Napoli 46%	6/5	6/5
Draw 1-1 11%	11/2	6/1
Napoli 2-1 9%	8/1	15/2
Napoli 1-0 8%	9/1 5%	17/2 6%
PSV 2-1 7%	11/1	9/1
Napoli 2-0 7%	11/1	10/1
PSV 1-0 6%	12/1 8%	10/1
Draw 2-2 6%	10/1 8%	10/1
Napoli 3-1 5%	16/1	12/1
Draw 0-0 5%	12/1	11/1
PSV 2-0 4%	18/1 12%	14/1
Napoli 3-0 4%	20/1	16/1
Napoli 3-2 3%	22/1	16/1 11%
PSV 3-1 3%	22/1	18/1
PSV 3-2 3%	28/1	20/1
Napoli 4-1 2%	33/1	25/1
Over 2.5 Goals 58%	4/6 3%	8/13 3%
Under 2.5 Goals 42%	6/5 5%	23/20 2%
Home 1st Goal 47%	11/10	23/20
Away 1st Goal 51%	4/5	4/5
No 1st Goal 3%	12/1	10/1
BTTS - Yes 60%	4/7	4/7 2%
BTTS - No 40%	5/4	13/10 2%
BTTS - Home Win 17%	9/2	19/5 4%
BTTS - Draw 19%	3/1	16/5 3%
BTTS - Away Win 24%	3/1	13/5 3%
Home/draw 55%	4/6	4/6
Away/draw 69%	1/3 2%	4/11
Home/away 76%	1/3	2/7
Over 1.5 Goals 81%	1/5 2%	1/5 2%
Under 1.5 Goals 19%	7/2 4%	16/5 5%
Over 3.5 Goals 36%	13/8 4%	6/4 5%
Under 3.5 Goals 64%	1/2 4%	10/21 3%
Over 4.5 Goals 19%	7/2 10%	17/5 4%
Under 4.5 Goals 81%	1/5 3%	2/11 1%
Over 5.5 Goals 9%	8/1 10%	7/1 6%
Under 5.5 Goals 91%	1/14 1%	1/18
Over 0.5 Goals 95%	1/25	1/33
Under 0.5 Goals 5%	12/1	10/1
Home DNB 47%	5/4	6/5
Away DNB 62%	4/7	3/5
PSV win to nil 14%	11/2	-
Napoli win to nil 21%	10/3	-
PSV / PSV 16%	4/1	19/5
PSV / Napoli 4%	22/1	16/1 11%
PSV / Draw 6%	12/1	11/1
Draw / PSV 11%	6/1	6/1
Draw / Napoli 15%	9/2	17/4
Draw / Draw 14%	5/1	9/2 5%
Napoli / PSV 3%	25/1	20/1
Napoli / Napoli 23%	5/2	12/5 3%
Napoli / Draw 6%	12/1	11/1

Win / draw / win Champions League table

BTTS yes BTTS no BTTS yes BTTS no Won Draw Lost Won Draw Lost Won Draw Lost Won Draw Lost Won Draw Lost Won Draw Lost Won Draw Lost Over 0.5 Under 0.5 Over 1.5 Under 1.5 Over 2.5 Under 2.5 Over 3.5 Under 3.5 Over 4.5 Under 4.5 Over 5.5 Under 5.5 For 0-0 Against Won Draw Lost	PSV Napoli
Results by League Table

	TEAM	PLD	W	D	L	GD	PTS	HOME	AWAY	HOME	AWAY
1	Bayern	2	2	0	0	6	6	Jan 28	-	-	-
2	Real Madrid	2	2	0	0	6	6	-	-	-	-
3	PSG	2	2	0	0	5	6	-	-	-	-
4	Inter	2	2	0	0	5	6	-	-	-	-
5	Arsenal	2	2	0	0	4	6	-	-	-	-
6	Qarabag	2	2	0	0	3	6	-	-	Nov 25	-
7	Dortmund	2	1	1	0	3	4	-	-	-	-
8	Man City	2	1	1	0	2	4	-	-	-	l 2-0A
9	Spurs	2	1	1	0	1	4	-	-	-	-
10	A.Madrid	2	1	0	1	3	3	Dec 9	-	-	-
11	Newcastle	2	1	0	1	3	3	-	Jan 21	-	-
12	Marseille	2	1	0	1	3	3	-	-	-	-
13	Brugge	2	1	0	1	2	3	-	-	-	-
14	S. Lisbon	2	1	0	1	2	3	-	-	w 2-1F	-
15	E.Frankfurt	2	1	0	1	0	3	-	-	Nov 4	-
16	Barcelona	2	1	0	1	0	3	-	-	-	-
17	Liverpool	2	1	0	1	0	3	-	Nov 26	-	-
18	Chelsea	2	1	0	1	-1	3	-	-	Jan 28	-
19	Napoli	2	1	0	1	-1	3	Oct 21	-	-	-
20	Union SG	2	1	0	1	-2	3	l 1-3A	-	-	-
21	Galatasaray	2	1	0	1	-3	3	-	-	-	-
22	Atalanta	2	1	0	1	-3	3	-	-	-	-
23	Juventus	2	0	2	0	0	2	-	-	-	-
24	Bodø	2	0	2	0	0	2	-	-	-	-
25	Leverkusen	2	0	2	0	0	2	-	d 1-1A	-	-
26	Villarreal	2	0	1	1	-1	1	-	-	-	-
27	PSV	2	0	1	1	-2	1	-	-	-	Oct 21
28	Kobenhavn	2	0	1	1	-2	1	-	-	-	Jan 20
29	Olympiakos	2	0	1	1	-2	1	-	Nov 4	-	-
30	Monaco	2	0	1	1	-3	1	-	-	-	-
31	Slavia	2	0	1	1	-3	1	-	-	-	-
32	Paphos	2	0	1	1	-4	1	-	-	-	-
33	Benfica	2	0	0	2	-2	0	-	-	-	Dec 10
34	A.Bilbao	2	0	0	2	-5	0	-	-	-	-
35	Ajax	2	0	0	2	-6	0	-	-	-	-
36	Kairat Almaty	2	0	0	2	-8	0	-	-	-	-

	Next round
	Play Off

Win / draw / win form

Home

Overall

Goals: Scored

Conceded

Games: Scored

19 / 20

Conceded

15 / 20

Clean sheets

5 / 20

Failed to score

1 / 20

Won

Draw

HOME FORM Win / Draw / Win
PSV	1 - 3	Union SG
PSV	1 - 7	Arsenal
PSV	2 - 1	Juventus
PSV	3 - 2	Liverpool
PSV	3 - 2	Shakhtar
PSV	4 - 0	Girona
PSV	1 - 1	S. Lisbon
PSV	1 - 1	Dortmund
PSV	1 - 1	Arsenal
PSV	1 - 0	Lens
PSV	2 - 2	Sevilla
PSV	5 - 1	Rangers
PSV	4 - 1	Sturm Graz
PSV	2 - 0	Sevilla
PSV	2 - 0	Arsenal
PSV	5 - 0	Zurich
PSV	1 - 1	Bodø
PSV	0 - 1	Rangers
PSV	2 - 2	Monaco
PSV	1 - 2	Leicester

Goals: Scored

Conceded

Games: Scored

18 / 20

Conceded

18 / 20

Clean sheets

2 / 20

Failed to score

2 / 20

Won

Draw

Lost

OVERALL FORM Win / Draw / Win
A	PSV	1 - 1	Leverkusen
H	PSV	1 - 3	Union SG
A	PSV	2 - 2	Arsenal
H	PSV	1 - 7	Arsenal
H	PSV	2 - 1	Juventus
A	PSV	1 - 2	Juventus
H	PSV	3 - 2	Liverpool
A	PSV	3 - 2	Red Star Bel.
A	PSV	0 - 1	Brest
H	PSV	3 - 2	Shakhtar
H	PSV	4 - 0	Girona
A	PSV	1 - 1	PSG
H	PSV	1 - 1	S. Lisbon
A	PSV	1 - 3	Juventus
A	PSV	0 - 2	Dortmund
H	PSV	1 - 1	Dortmund
H	PSV	1 - 1	Arsenal
A	PSV	3 - 2	Sevilla
H	PSV	1 - 0	Lens
A	PSV	1 - 1	Lens

Away

Overall

Goals: Scored

Conceded

Games: Scored

16 / 20

Conceded

15 / 20

Clean sheets

5 / 20

Failed to score

4 / 20

Won

Draw

Lost

AWAY FORM Win / Draw / Win
Man City	2 - 0	Napoli
Barcelona	3 - 1	Napoli
Real Madrid	4 - 2	Napoli
Union Berlin	0 - 1	Napoli
Braga	1 - 2	Napoli
Milan	1 - 0	Napoli
E.Frankfurt	0 - 2	Napoli
Liverpool	0 - 0	Napoli
Ajax	1 - 6	Napoli
Rangers	0 - 3	Napoli
Barcelona	1 - 1	Napoli
Spartak M	2 - 1	Napoli
L. Warsaw	1 - 4	Napoli
Leicester	2 - 2	Napoli
Granada	2 - 0	Napoli
AZ Alkmaar	1 - 1	Napoli
Rijeka	1 - 2	Napoli
R.Sociedad	0 - 1	Napoli
Barcelona	3 - 1	Napoli
Liverpool	1 - 1	Napoli

Goals: Scored

Conceded

Games: Scored

17 / 20

Conceded

13 / 20

Clean sheets

7 / 20

Failed to score

3 / 20

Won

Lost

OVERALL FORM Win / Draw / Win
H	Napoli	2 - 1	S. Lisbon
A	Napoli	0 - 2	Man City
A	Napoli	1 - 3	Barcelona
H	Napoli	1 - 1	Barcelona
H	Napoli	2 - 0	Braga
A	Napoli	2 - 4	Real Madrid
H	Napoli	1 - 1	Union Berlin
A	Napoli	1 - 0	Union Berlin
H	Napoli	2 - 3	Real Madrid
A	Napoli	2 - 1	Braga
H	Napoli	1 - 1	Milan
A	Napoli	0 - 1	Milan
H	Napoli	3 - 0	E.Frankfurt
A	Napoli	2 - 0	E.Frankfurt
A	Napoli	0 - 0	Liverpool
H	Napoli	3 - 0	Rangers
H	Napoli	4 - 2	Ajax
A	Napoli	6 - 1	Ajax
A	Napoli	3 - 0	Rangers
H	Napoli	4 - 1	Liverpool

Goal Statistics

Napoli have been steady in front of goal of late, finding the net in 7 consecutive Champions League games. Their PG of 1.7 against PSV on Tuesday suggests that run is likely to continue.

	PSV 27th	Napoli 19th
	Kickoff prediction
Kickoff prediction	1.3 goals	1.7 goals
	Scoring probability
Scoring probability	0 26% 1 35% 2 24% 3 11% 4+ There is a 74% probability that PSV will score 1 or more goals	0 19% 1 31% 2 26% 3 15% 4+ 9% There is a 81% probability that Napoli will score 1 or more goals

	20 home / away league games
20 home / away league games	+14 PSV have scored 14% more goals at home than predicted	+4 Napoli’s goalscoring when away has been inline with predictions
	2.1 average goals scored	1.6 average goals scored
	1.4 conceded	1.3 conceded

Attack defence ratings
Champions League - 2025/2025 season

18%

better

PSV

NAP

view stats

Games scored	16		15
Failed to score	2		3
Scored first	11		14
Goals scored	51		28
Avg. goals scored	2.6		1.4
Avg. shots per game	13		8
Avg. shots per goal	5		6
Conversion rate for	20		18
Avg. XG for	2.5		1.6
KickOff rating		+18%

PSV

NAP

46%

better

view stats

Games conceded	15		9
Clean sheets	3		9
Conceded first	7		2
Goals conceded	25		12
Avg. goals conceded	1.3		0.6
Avg. shots/game conceded	7		7
Avg. shots/goal conceded	6		11
Conversion rate against	18%		9%
Avg. XG against	1.1		1.1
KickOff rating		+46%

The line-ups for the Champions League match between PSV v Napoli will show here when available.

PSV Champions League squad statistics 2025

Overall

Attack

Defence

Most starts	Most goals	Most assists	Most cards
2	1	1	1
M Kovář	I Saibari	G Til	I Saibari

Players	Appserances	goals	Assists	cards
M Kovář GLK	2			-
A Salah-Eddine DEF	2			-
A Obispo DEF	2			-
Y. Gąsiorowski Hernandis DEF	2			-
R Flamingo DEF	2			-
I Saibari MID	2	1		1 -
J Veerman MID	2			-
J Schouten MID	2			-
G Til MID	2		1	1 -
I Perisic FWD	2			-
D Man FWD	2			-
S Dest DEF	1			-
M Júnior DEF	1			-
P Wanner MID	1			-
E Bajraktarevic FWD	1			-
M Boadu FWD	1			-
C Driouech FWD	1			-
R Pepi FWD	1			-
R Bommel FWD	1	1		-

Most goals	Most shots on target	Most assists	Most big chances
1	2	1	1
I Saibari	R Pepi	G Til	A Salah-Eddine

Players	goals	shots on	Assists	big chances
I Saibari MID	1	1
R Bommel FWD	1	1		1
A Salah-Eddine DEF				1
G Til MID			1	1
I Perisic FWD				1
D Man FWD				1
R Pepi FWD		2

Most passes	Most tackles	Most duels won
158	7	15
J Veerman	R Flamingo	I Saibari

Players	passes	tackles	duels won
J Veerman MID	158	1	7
Y. Gąsiorowski Hernandis DEF	125	6	13
R Flamingo DEF	92	7	10
M Kovář GLK	90		3
A Salah-Eddine DEF	88	1	6
J Schouten MID	76	5	6
A Obispo DEF	73	4	8
M Júnior DEF	65	4	6
I Perisic FWD	63		3
S Dest DEF	62	2	8
I Saibari MID	59	4	15
D Man FWD	40	1	5
G Til MID	38	2	4
R Bommel FWD	22	4	12
R Pepi FWD	18
E Bajraktarevic FWD	13	3	3
P Wanner MID	9		1
C Driouech FWD	8

Napoli Champions League squad statistics 2025

Overall

Attack

Defence

Most starts	Most goals	Most assists	Most cards
2	2	2	1
V Milinković-Savić	R Höjlund	K Bruyne	M Politano

Players	Appserances	goals	Assists	cards
V Milinković-Savić GLK	2			-
M Olivera DEF	2			-
L Spinazzola DEF	2			-
J Jesus DEF	2			-
S Beukema DEF	2			-
K Bruyne MID	2		2	-
S Lobotka MID	2			-
F Anguissa MID	2			-
S McTominay MID	2			-
B Gilmour MID	2			-
R Höjlund FWD	2	2		-
D Neres FWD	2			-
M Politano FWD	2			1 -
A Buongiorno DEF	1			-
G Lorenzo DEF	1			1
M Gutiérrez DEF	1			-
E Elmas FWD	1			-
L Lucca FWD	1			-
N Lang FWD	1			-

Most goals	Most shots on target	Most assists	Most big chances
2	2	2	2
R Höjlund	R Höjlund	K Bruyne	K Bruyne

Players	goals	shots on	Assists	big chances
R Höjlund FWD	2	2
S Beukema DEF		1
K Bruyne MID			2	2
M Politano FWD		1		1

Most passes	Most tackles	Most duels won
125	5	10
S Beukema	S Lobotka	S McTominay

Players	passes	tackles	duels won
S Beukema DEF	125	2	7
S Lobotka MID	99	5	7
J Jesus DEF	81	2	3
L Spinazzola DEF	75	3	3
V Milinković-Savić GLK	72		3
F Anguissa MID	61	2	5
K Bruyne MID	54	2	7
M Politano FWD	48	2	5
S McTominay MID	35	2	10
A Buongiorno DEF	29
R Höjlund FWD	24		8
B Gilmour MID	23
M Gutiérrez DEF	22	2	3
D Neres FWD	14	1	3
M Olivera DEF	9	4	4
G Lorenzo DEF	7
N Lang FWD	7	1	2
E Elmas FWD	6
L Lucca FWD		1	1