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Olympiakos v PSV : Champions League match betting preview, prediction and odds

Tue 4th Nov, 20:00 BST, Georgios Karaiskakis Stadium, Piraeus

The Champions League is the focus for both Olympiakos and PSV on Tuesday night, as managers Jose Luis Mendilibar and Peter Bosz go head to head at the Georgios Karaiskakis Stadium. Statistics for our tip of are shown below, including head to head (H2H) history. Changing the market using the tabs below changes all statistics and the odds, so be sure to have a browse to find the best bet for you.


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Best Tip: Both teams to score

After looking at the KickOff match predictions, bookies' odds and relevant stats, there's one market which jumps out ahead of the rest for this fixture: both teams to score. In Olympiakos and PSV we have two sides going head-to-head that regularly score, but equally have trouble shutting the opposition out, and we expect them to maintain that reputation on Tuesday night. BTTS – yes best odds: 1.67.

In-Play
Win / Draw / Win
Over / Under 1.5 Goals
Over / Under 2.5 Goals
Over / Under 3.5 Goals
Win To Nil
Both Teams To Score
Correct Score
Both Teams To Score & Result
Double Chance
Half Time / Full Time
Over / Under 0.5 Goals
Over / Under 4.5 Goals
Over / Under 5.5 Goals
Draw No Bet
Team To Score First

Checkout the hundreds of tips picked but our top win/draw/win tipsters

Change odds
Predictions Add Bet365 Coral
Olympiakos
43%
27/2013/10
Draw
24%
5/25/2
PSV
33%
19/1019/10
Draw 1-1
11%
6/16/1
Olympiakos 2-1
9%
17/28/1
Olympiakos 1-0
8%
9/117/2
PSV 2-1
8%
10/19/1
PSV 1-0
7%
11/110/1
Olympiakos 2-0
6%
12/111/1
Draw 2-2
6%
11/110/1
Olympiakos 3-1
5%
16/114/1
Draw 0-0
5%
12/110/1
PSV 2-0
5%
16/114/1
PSV 3-1
4%
20/116/1
Olympiakos 3-0
4%
22/118/1
Olympiakos 3-2
3%
22/118/1
PSV 3-2
3%
25/120/1
PSV 3-0
2%
28/122/1
Over 2.5 Goals
59%
4/64/6
Under 2.5 Goals
41%
6/511/10
Home 1st Goal
50%
5/617/20
Away 1st Goal
47%
1/111/10
No 1st Goal
3%
12/19/1
BTTS - Yes
61%
4/74/7
BTTS - No
39%
5/413/10
BTTS - Home Win
24%
3/114/5
BTTS - Draw
19%
10/316/5
BTTS - Away Win
18%
4/118/5
Home/draw
67%
2/52/5
Away/draw
57%
4/73/5
Home/away
76%
2/73/10
Over 1.5 Goals
81%
2/92/9
Under 1.5 Goals
19%
10/33/1
Over 3.5 Goals
37%
7/48/5
Under 3.5 Goals
64%
4/94/9
Over 4.5 Goals
19%
4/17/2
Under 4.5 Goals
81%
1/61/6
Over 5.5 Goals
9%
9/115/2
Under 5.5 Goals
91%
1/161/18
Over 0.5 Goals
95%
1/251/33
Under 0.5 Goals
5%
12/110/1
Home DNB
60%
4/613/20
Away DNB
49%
11/1011/10
Olympiakos win to nil
20%
7/2-
PSV win to nil
14%
5/1-
Olympiakos / Olympiakos
22%
11/413/5
Olympiakos / PSV
3%
25/120/1
Olympiakos / Draw
6%
12/111/1
Draw / Olympiakos
14%
5/19/2
Draw / PSV
12%
6/111/2
Draw / Draw
14%
5/117/4
PSV / Olympiakos
4%
22/118/1
PSV / PSV
18%
7/27/2
PSV / Draw
6%
12/111/1
Win / draw / win Champions League table
Won
Draw
Lost
Olympiakos
PSV
Results by League Table
TEAM PLD W D L GD PTS HOME AWAY HOME AWAY
1
PSG3300109 
-
-
-
-
2
Bayern3300109 
-
-
Jan 28
-
3
Inter330099 
-
-
-
-
4
Arsenal330089 
-
l
 
2-0A
-
-
5
Real Madrid330079 
Nov 26
-
-
-
6
Dortmund321057 
-
-
-
-
7
Man City321047 
-
-
-
-
8
Newcastle320166 
-
-
-
Jan 21
9
Barcelona320156 
-
l
 
6-1A
-
-
10
Liverpool320146 
-
-
-
Nov 26
11
S. Lisbon320136 
-
-
-
-
12
Chelsea320136 
-
-
-
-
13
Qarabag320116 
-
-
-
-
14
Galatasaray3201-16 
-
-
-
-
15
Spurs312015 
-
-
-
-
16
PSV311124 
Nov 4
-
-
-
17
Atalanta3111-34 
-
-
-
-
18
Marseille310223 
-
-
-
-
19
A.Madrid3102-13 
-
-
Dec 9
-
20
Brugge3102-23 
-
-
-
-
21
A.Bilbao3102-33 
-
-
-
-
22
E.Frankfurt3102-43 
-
-
-
-
23
Napoli3102-53 
-
-
w
 
6-2A
-
24
Union SG3102-63 
-
-
l
 
1-3A
-
25
Juventus3021-12 
-
-
-
-
26
Bodø3021-22 
-
-
-
-
27
Monaco3021-32 
-
-
-
-
28
Slavia3021-32 
-
-
-
-
29
Paphos3021-42 
d
 
0-00-0
-
-
-
30
Leverkusen3021-52 
Jan 20
-
-
d
 
1-1A
31
Villarreal3012-31 
-
-
-
-
32
Kobenhavn3012-41 
-
-
-
-
33
Olympiakos3012-71 
-
-
-
Nov 4
34
Kairat Almaty3012-81 
-
Dec 9
-
-
35
Benfica3003-50 
-
-
-
-
36
Ajax3003-100 
-
Jan 28
-
-
Next round
Play Off
Win / draw / win form
Olympiakos 33RD
20 league games
Home
Overall
Goals: Scored
30
Conceded
24
Games: Scored
14 / 20
Conceded
12 / 20
Clean sheets
8 / 20
Failed to score
6 / 20
Won
10
Draw
5
Lost
5
Goals: Scored
26
Conceded
25
Games: Scored
12 / 20
Conceded
11 / 20
Clean sheets
9 / 20
Failed to score
8 / 20
Won
9
Draw
5
Lost
6
PSV 16TH
20 league games
Away
Overall
Goals: Scored
28
Conceded
33
Games: Scored
14 / 20
Conceded
19 / 20
Clean sheets
1 / 20
Failed to score
6 / 20
Won
5
Draw
8
Lost
7
Goals: Scored
36
Conceded
36
Games: Scored
18 / 20
Conceded
18 / 20
Clean sheets
2 / 20
Failed to score
2 / 20
Won
8
Draw
6
Lost
6
Goal Statistics

Olympiakos have been steady in front of goal of late, finding the net in 30 consecutive Champions League outings. Their PG of 1.6 against PSV on Tuesday suggests they're likely to extend that run.

Olympiakos 33rd PSV 16th
Kickoff prediction
Kickoff prediction
1.6
goals
1.4
goals
Scoring probability
Scoring probability
0
19%
1
32%
2
26%
3
14%
4+
9%
There is a 81% probability that Olympiakos will score 1 or more goals
0
25%
1
34%
2
24%
3
11%
4+
There is a 75% probability that PSV will score 1 or more goals
 
20 home / away league games
20 home / away league games
-17
Olympiakos have scored 17% fewer goals at home than predicted
=0
PSV’s goalscoring when away has been inline with predictions
1.5
average goals scored
1.4
average goals scored
1.2
conceded
1.7
conceded
 
Attack defence ratings
Champions League - 2025/2025 season
Olympiakos
PG (predicted goals)
PSV
1.6
1.4
Attack rating
OLY
PSV
22%
better
view stats
Games scored17
18
Failed to score3
2
Scored first12
12
Goals scored34
60
Avg. goals scored1.7
3
Avg. shots per game10
15
Avg. shots per goal6
5
Conversion rate for17
21
Avg. XG for1.6
2.6
KickOff rating
+22%
Defence rating
19%
better
OLY
PSV
view stats
Games conceded10
17
Clean sheets10
3
Conceded first7
8
Goals conceded23
27
Avg. goals conceded1.2
1.4
Avg. shots/game conceded6
8
Avg. shots/goal conceded5
6
Conversion rate against19%
17%
Avg. XG against1.7
1.1
KickOff rating
+19%

The line-ups for the Champions League match between Olympiakos v PSV will show here when available.

Olympiakos Champions League squad statistics 2025
Overall
Attack
Defence
Most startsMost goalsMost assistsMost cards
3102
P RetsosA KaabiS Hezze
PlayersAppserancesgoalsAssistscards
P Retsos DEF3
-
F Ortega DEF3
-
Costinha DEF3
-
L Pirola DEF3
1
-
S Hezze MID3
1
1
C. Mouzakitis MID3
-
Chiquinho MID3
-
D García MID3
2
-
D Podence FWD3
1
-
M Taremi FWD3
1
-
A Kaabi FWD31
-
K Tzolakis GLK2
-
G Biancone DEF2
-
G Strefezza FWD2
1
-
G Martins FWD2
-
A Paschalakis GLK1
-
B Onyemaechi DEF1
-
Rodinei DEF1
-
D. Santos Nascimento MID1
-
L Scipioni MID1
-
S. Pnevmonidis FWD1
-
R Yaremchuk FWD1
-
PSV Champions League squad statistics 2025
Overall
Attack
Defence
Most startsMost goalsMost assistsMost cards
3222
M KovářI SaibariG TilI Saibari
PlayersAppserancesgoalsAssistscards
M Kovář GLK3
-
A Salah-Eddine DEF3
-
A Obispo DEF3
-
Y. Gąsiorowski Hernandis DEF3
1
-
R Flamingo DEF3
-
J Schouten MID3
-
G Til MID32
1
-
I Saibari MID32
2
-
J Veerman MID31
1
-
I Perisic FWD3
-
D Man FWD32
-
S Dest DEF2
-
M Júnior DEF21
-
P Wanner MID2
-
C Driouech FWD211
1
-
R Pepi FWD211
-
M Boadu FWD1
-
R Bommel FWD11
-
E Bajraktarevic FWD1
-