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Villarreal v Napoli : Champions League match betting preview, prediction and odds

Tue 13th Oct, 20:00 BST, Estadio de la Cerámica, Castellón

We’ve Champions League action to look forward to on Tuesday night, as Iñigo Pérez Soto and his Villarreal side host Massimiliano Allegri’s Napoli at the Estadio de la Cerámica. For each and every Champions League match preview, KickOff explores the statistics for seventeen major betting markets. Meaningful stats, including head-to-head results, are then published alongside the best odds.


Want to know who’s consistently beating the odds? Check out the Top Champions League Tipsters and see the most profitable experts for this season!

If you’re keen on betting across various leagues and markets, our Live Bets page showcases active accumulator bets and real-time tips.

Best Tip: Both teams to score

Analysing the KickOff match predictions, bookmakers' odds and relevant stats, there's one market which jumps out ahead of the rest for this fixture: both teams to score. In Villarreal and Napoli we have two sides going head-to-head that regularly score, but equally have trouble shutting the opposition out, and we expect them to show themselves again on Tuesday night. BTTS – yes best odds: 1.53.

In-Play
Win / Draw / Win
Over / Under 1.5 Goals
Over / Under 2.5 Goals
Over / Under 3.5 Goals
Win To Nil
Both Teams To Score
Correct Score
Both Teams To Score & Result
Double Chance
Half Time / Full Time
Over / Under 0.5 Goals
Over / Under 4.5 Goals
Over / Under 5.5 Goals
Draw No Bet
Team To Score First
If you’re looking for a winner in this match, we think Villarreal are the most likely. Our predictive algorithm gives them a 45% chance of victory, and the bookies have them at a best price of 2.20.

Checkout the hundreds of tips picked but our top win/draw/win tipsters

Change odds
Predictions Add Bet365 Coral
Villarreal
45%
2.15
9%
-
Draw
24%
3.50
3%
-
Napoli
31%
3.25
12%
-
Draw 1-1
11%
6.50
7%
-
Villarreal 2-1
9%
9.00
5%
-
Villarreal 1-0
8%
9.00
18%
-
Napoli 2-1
7%
12.00
9%
-
Villarreal 2-0
7%
11.00
15%
-
Napoli 1-0
7%
11.00
15%
-
Draw 2-2
6%
13.00
18%
-
Villarreal 3-1
5%
17.00-
Draw 0-0
5%
12.00
20%
-
Napoli 2-0
4%
17.00-
Villarreal 3-0
4%
21.00
9%
-
Villarreal 3-2
3%
23.00
10%
-
Napoli 3-1
3%
23.00
10%
-
Napoli 3-2
3%
29.00
26%
-
Villarreal 4-1
2%
34.00-
Over 2.5 Goals
58%
1.80
8%
-
Under 2.5 Goals
42%
2.00
9%
-
Home 1st Goal
51%
1.80
2%
-
Away 1st Goal
46%
2.10
5%
-
No 1st Goal
3%
12.00
20%
-
BTTS - Yes
60%
1.67
9%
-
BTTS - No
40%
2.10
12%
-
BTTS - Home Win
24%
4.00-
BTTS - Draw
19%
4.33
8%
-
BTTS - Away Win
17%
6.00
26%
-
Home/draw
69%
1.33
5%
-
Away/draw
55%
1.67
6%
-
Home/away
76%
1.29
1%
-
Over 1.5 Goals
80%
1.25
4%
-
Under 1.5 Goals
20%
4.00
11%
-
Over 3.5 Goals
36%
3.00
20%
-
Under 3.5 Goals
64%
1.40
9%
-
Over 4.5 Goals
19%
5.50
22%
-
Under 4.5 Goals
81%
1.14
5%
-
Over 5.5 Goals
9%
11.00
22%
-
Under 5.5 Goals
91%
1.05
2%
-
Over 0.5 Goals
95%
1.05
2%
-
Under 0.5 Goals
5%
11.00
27%
-
Home DNB
62%
1.57
6%
-
Away DNB
47%
2.25
7%
-
Villarreal win to nil
21%
4.00
20%
-
Napoli win to nil
14%
6.00-
Villarreal / Villarreal
24%
3.50
7%
-
Villarreal / Napoli
3%
29.00
26%
-
Villarreal / Draw
6%
13.00-
Draw / Villarreal
15%
5.50
8%
-
Draw / Napoli
11%
7.00-
Draw / Draw
14%
5.50
8%
-
Napoli / Villarreal
4%
23.00-
Napoli / Napoli
17%
5.00
11%
-
Napoli / Draw
6%
15.00
15%
-
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Win / draw / win form
7
Villarreal have lost 7 consecutive european games
Villarreal 22ND
20 league games
Home
Overall
7
Goals: Scored
36
Conceded
29
Games: Scored
16 / 20
Conceded
15 / 20
Clean sheets
5 / 20
Failed to score
4 / 20
Won
8
Draw
6
Lost
6
HOME FORM Win / Draw / Win
Villarreal1 - 2Ajax
Villarreal2 - 3Kobenhavn
Villarreal0 - 2Man City
Villarreal2 - 2Juventus
Villarreal3 - 1Marseille
Villarreal0 - 0M. Haifa
Villarreal3 - 2Panathinaikos
Villarreal1 - 0Rennes
Villarreal0 - 1Anderlecht
Villarreal2 - 2Beer Sheva
Villarreal5 - 0Austria Wien
Villarreal4 - 3Lech Poznan
Villarreal4 - 2Hajduk Split
Villarreal2 - 3Liverpool
Villarreal1 - 0Bayern
Villarreal1 - 1Juventus
Villarreal0 - 2Man Utd
Villarreal2 - 0Young Boys
Villarreal2 - 2Atalanta
Villarreal1 - 1Man Utd
Goals: Scored
20
Conceded
38
Games: Scored
10 / 20
Conceded
18 / 20
Clean sheets
2 / 20
Failed to score
10 / 20
Won
5
D
3
Lost
12
OVERALL FORM Win / Draw / Win
AVillarreal2 - 3Dortmund
AVillarreal0 - 3Leverkusen
HVillarreal1 - 2Ajax
HVillarreal2 - 3Kobenhavn
AVillarreal0 - 4Dortmund
AVillarreal0 - 1Paphos
HVillarreal0 - 2Man City
HVillarreal2 - 2Juventus
AVillarreal0 - 1Spurs
HVillarreal3 - 1Marseille
AVillarreal0 - 4Marseille
AVillarreal3 - 2Rennes
HVillarreal0 - 0M. Haifa
HVillarreal3 - 2Panathinaikos
AVillarreal2 - 1M. Haifa
HVillarreal1 - 0Rennes
AVillarreal0 - 2Panathinaikos
HVillarreal0 - 1Anderlecht
AVillarreal1 - 1Anderlecht
AVillarreal0 - 3Lech Poznan
Napoli 28TH
20 league games
Away
Overall
Goals: Scored
31
Conceded
31
Games: Scored
15 / 20
Conceded
16 / 20
Clean sheets
4 / 20
Failed to score
5 / 20
Won
7
Draw
5
Lost
8
AWAY FORM Win / Draw / Win
Kobenhavn1 - 1Napoli
Benfica2 - 0Napoli
PSV6 - 2Napoli
Man City2 - 0Napoli
Barcelona3 - 1Napoli
Real Madrid4 - 2Napoli
Union Berlin0 - 1Napoli
Braga1 - 2Napoli
Milan1 - 0Napoli
E.Frankfurt0 - 2Napoli
Liverpool0 - 0Napoli
Ajax1 - 6Napoli
Rangers0 - 3Napoli
Barcelona1 - 1Napoli
Spartak M2 - 1Napoli
L. Warsaw1 - 4Napoli
Leicester2 - 2Napoli
Granada2 - 0Napoli
AZ Alkmaar1 - 1Napoli
Rijeka1 - 2Napoli
Goals: Scored
25
Conceded
31
Games: Scored
15 / 20
Conceded
15 / 20
Clean sheets
5 / 20
Failed to score
5 / 20
Won
6
Draw
5
Lost
9
OVERALL FORM Win / Draw / Win
HNapoli0 - 1Arsenal
HNapoli2 - 3Chelsea
ANapoli1 - 1Kobenhavn
ANapoli0 - 2Benfica
HNapoli2 - 0Qarabag
HNapoli0 - 0E.Frankfurt
ANapoli2 - 6PSV
HNapoli2 - 1S. Lisbon
ANapoli0 - 2Man City
ANapoli1 - 3Barcelona
HNapoli1 - 1Barcelona
HNapoli2 - 0Braga
ANapoli2 - 4Real Madrid
HNapoli1 - 1Union Berlin
ANapoli1 - 0Union Berlin
HNapoli2 - 3Real Madrid
ANapoli2 - 1Braga
HNapoli1 - 1Milan
ANapoli0 - 1Milan
HNapoli3 - 0E.Frankfurt
Win / draw / win head to head (H2H)
League games at Villarreal since 2011
Villarreal
Napoli
Goals: Scored
3
3
Games: Scored
2 / 3
2 / 3
Clean sheets
1 / 3
1 / 3
VIL
2
NAP
1
FIXTURE HISTORY AT Villarreal
Villarreal1 - 0
0 - 2Napoli
Villarreal2 - 1
League games at Napoli since 2011
Napoli
Villarreal
Goals: Scored
3
1
Games: Scored
2 / 3
1 / 3
Clean sheets
2 / 3
1 / 3
D
2
NAP
1
FIXTURE HISTORY AT Napoli
Draw1 - 1Draw
Napoli2 - 0
Draw0 - 0Draw
Goal Statistics
Villarreal 22nd Napoli 28th
Kickoff prediction
Kickoff prediction
1.7
goals
1.3
goals
Scoring probability
Scoring probability
0
19%
1
31%
2
26%
3
15%
4+
9%
There is a 81% probability that Villarreal will score 1 or more goals
0
26%
1
35%
2
24%
3
11%
4+
There is a 74% probability that Napoli will score 1 or more goals
 
20 home / away league games
20 home / away league games
-3
Villarreal’s goalscoring at home has been inline with predictions
=0
Napoli’s goalscoring when away has been inline with predictions
1.8
average goals scored
1.6
average goals scored
1.5
conceded
1.6
conceded
 
Attack defence ratings
Champions League - 2026/2027 season
Villarreal
PG (predicted goals)
Napoli
1.7
1.3
Attack rating
3%
better
VIL
NAP
view stats
Games scored16
17
Failed to score4
3
Scored first11
13
Goals scored37
30
Avg. goals scored1.9
1.5
Avg. shots per game10
10
Avg. shots per goal5
7
Conversion rate for18
15
Avg. XG for1.9
1.4
KickOff rating
+3%
Defence rating
VIL
NAP
43%
better
view stats
Games conceded20
11
Clean sheets0
9
Conceded first9
6
Goals conceded30
18
Avg. goals conceded1.5
0.9
Avg. shots/game conceded9
10
Avg. shots/goal conceded6
11
Conversion rate against17%
9%
Avg. XG against1.3
1.2
KickOff rating
+43%

The line-ups for the Champions League match between Villarreal v Napoli will show here when available.

Villarreal Champions League squad statistics 2026/2027
Overall
Attack
Defence
Most startsMost goalsMost assistsMost cards
1111
S MouriñoS MouriñoG MikautadzeS Mouriño
Line-upAppserancesgoalsAssistscards
L Júnior GLK
-
S Mouriño DEF11
1
-
P. Navarro Badenes DEF1
1
-
R Veiga DEF1
-
C Romero DEF
-
S Comesaña MID1
-
N Saliba MID1
-
P Gueye MID1
-
A Moleiro MID1
-
G Moreno FWD1
-
G Mikautadze FWD11
-
Subs
R Gómez GLK
-
S Cardona DEF1
1
-
L Costa DEF
-
A Freeman DEF1
-
J Foyth DEF
-
A. Diatta MID1
-
Carlos Macià MID
-
I Akhomach FWD
-
A Pérez FWD
-
T Oluwaseyi FWD1
-
N. El Jmili Ben Hamou FWD
-
J. Gaitán Diaz FWD
-
Napoli Champions League squad statistics 2026/2027
Overall
Attack
Defence
Most startsMost goalsMost assistsMost cards
1001
A RrahmaniB Gilmour
Line-upAppserancesgoalsAssistscards
V Milinković-Savić GLK1
-
A Rrahmani DEF1
-
R Marín DEF1
-
B Badiashile  DEF
-
M Politano MID1
-
B Gilmour MID1
1
-
S McTominay MID
-
G Lorenzo MID1
-
Giovane FWD
-
K Bruyne FWD1
-
R Höjlund FWD1
-
Subs
A Meret GLK1
-
N Contini GLK
-
L Spinazzola DEF
-
S Beukema DEF
-
S Lobotka MID1
-
D Neres  FWD1
-
L Lucca FWD1
1
-
N Lang FWD
-